Awaiting Payment order status means that Orders are awaiting payment in AliExpress.
What to do?
1. In My Orders select status “Awaiting Payment” and then select all orders you want to pay for
2. Click on button Pay for N orders, or if you’re paying only for one order, press the drop-down menu on the order and select Pay
3. A new tab with AliExpress page will automatically open. Select the payment method you have saved on your AliExpress account and press Pay Now.