Awaiting Payment means that Orders are awaiting payment in AliExpress.
What to do?
1. Click filter “Awaiting Payment” and select all orders you want to pay for
2. Click card icon to Pay for selected orders, or if you’re paying only for one order press the drop-down menu on the order, More Actions, and select Pay
3. A new tab with AliExpress page will automatically open. Select the payment method you have saved on your Aliexpress account and press Pay Now.